韩占刚（Han Zhan-Gang）

理学博士，教授，博士生导师，化学与材料科学学院副院长

电子邮件：hanzg116@126.com；hanzg116@hebtu.edu.cn

所属专业：化学/无机化学

研究生招生方向：博士/化学；硕士/无机化学

教学工作：主讲本科生《无机化学》《无机化学实验》《无机合成化学》《综合实验》和研究生《多酸化学》《论文写作指导》《化学实验室安全教育》等课程。

科研工作：2016年获河北省杰出青年基金资助，入选河北省“三三三人才工程”第三层次人选名单。主要研究方向为新型多金属氧簇结构构筑、多酸型无机-有机杂化材料组装、多酸分子基功能材料、多酸催化化学。2010-2011年在澳大利亚Monash University和The University of New South Wales两所大学做高校教师访问学者，进行科研合作。在Chemical Science, Chemical Engineering Journal, Journal of Materials Chemistry A, Inorganic Chemistry等重要学术杂志上发表论文140余篇。主持及完成多项国家和省自然科学基金课题研究工作，在研国家自然科学基金面上项目和河北省自然科学基金面上项目各1项；作为第一完成人获得河北省自然科学三等奖1项。

OCRID：https://orcid.org/0000-0002-9758-6735

社会和学术兼职：

1. 河北省化学会常务理事

2. 石家庄市化学会秘书长

3. 河北师范大学学报自然科学版，编委

4. Polyoxometalate 编委

代表性研究论文：

1.      Wenting An, Xiujuan Zhang, Jiaqi Niu,Yuanyuan Ma∗, Zhangang Han∗, Unusual hexa-nuclear cadmiumcluster functionalized phosphomolybdate as effective photoelectrochemicalsensor for trace Cr(VI) detection, ChineseChemical Letters, 2022,doi.org/10.1016/j.cclet.2021.12.021.

https://linkinghub.elsevier.com/retrieve/pii/S1001841721010718

2.      Qi Wang, Ze-Yu Tian, Wen-Jing Cui, Na Hu,Si-Meng Zhang, Yuan-Yuan Ma*, Zhan-GangHan*, Hierarchical flower-like CoS2-MoS2 heterostructure spheres asefficient bifunctional electrocatalyst for overall water splitting, International Journal of Hydrogen Energy,2022, 47, 12629-2641.

https://linkinghub.elsevier.com/retrieve/pii/S0360319922005481

3.      Hao-Xue Bi, Lin Hou, Xiao-Yu Yin, Yuan-YuanMa,* and Zhan-Gang Han*. Central metals to guide the bandgap of hourglass-typepolyoxometalate hybrids as photocatalyst for the reduction of Cr(VI), Crystal Growth & Design, 2022, 22, 738-746.

https://pubs.acs.org/doi/10.1021/acs.cgd.1c01236?ref=PDF

4.      Ya-Qi Zhang, Lai-Yun Zhou, Yuan-Yuan Ma*,Kamran Dastafkan, Chuan Zhao, Lan-Zhi Wang*, Zhan-Gang Han*. Stable monovalent aluminum(I) in a reducedphosphomolybdate cluster as an active acid catalyst, Chemical Science, 2021,12(5), 1886-1890.

https://pubs.rsc.org/en/content/articlelanding/2021/SC/D0SC05277A

5.      Jia-Qi Niu, Wen-Ting An, Xiu-Juan Zhang,Yuan-Yuan Ma*, Zhan-Gang Han*,Ultra-trace determination of hexavalent chromium in a wide pH range triggeredby heterometallic Cu-Mn centers modified reduced phosphomolybdate hybrids, Chemical Engineering Journal, 2021, 418, 129408.

https://linkinghub.elsevier.com/retrieve/pii/S1385894721009967

6.      Jing Du, Yuanyuan Ma, Xing Xin, Hu Na,Yingnan Zhao, Huaqiao Tan,* Zhangang Han,* Yangguang Li,* Zhenhui Kang*.Reduced polyoxometalates and bipyridine ruthenium complex forming a tunablephotocatalytic system for high efficient CO2 reduction. ChemicalEngineering Journal, 2020, 398, 125518.

https://linkinghub.elsevier.com/retrieve/pii/S1385894720316466

7.      Na Hu, Jing Du, Yuan-Yuan Ma*, Wen-JingCui, Bo-Rong Yu, Zhan-Gang Han*,Yang-Guang Li, Unravelling the role of polyoxovanadates in electrocatalyticwater oxidation reaction: Active species or precursors, Applied Surface Science, 2021,540, 148306

https://www.sciencedirect.com/science/article/pii/S0169433220330634?via%3Dihub

8.      Ya-Qi Zhang, Lin Hou, Hao-Xue Bi, Xiao-XueFang, Yuan-Yuan Ma,* and Zhan-Gang Han*,Organic moiety-regulated photocatalytic performance of phosphomolybdate hybridsfor hexavalent chromium reduction, Chemistry—AnAsian Journal, 2021, 16,1584–1591.

https://onlinelibrary.wiley.com/doi/10.1002/asia.202100333

9.      Xuerui Tian, Yaqi Zhang, Yuanyuan Ma,*Qing Zhao and Zhangang Han*.Hourglass-type polyoxometalate-based crystalline materials as efficientcooperating photocatalysts for the reduction of Cr(VI) and oxidation of dyes. Catalysis Science &Technology, 2020, 10, 2593-2601.

https://pubs.rsc.org/en/content/articlelanding/2020/cy/d0cy00208a#!divAbstract

10.  Jia-Qi Niu, Yuan-Yuan Ma,* Xing Xin, and Zhan-Gang Han*. Rare earth ionencapsulated basket-like {Gd⊂P6MoV2MoVI16O73}cage as efficient electrochemical sensor and fluorescent probe for Cr(VI). Crystal Growth & Design, 2020, 20, 3584-3589.

https://pubs.acs.org/doi/10.1021/acs.cgd.0c00211

11.  Tong Zhou, Jie Zhang, Yuan-yuan Ma*, XiaoruGao, Qihui Xue, Yuanzhe Gao*, Zhan-gangHan*, A Bicadmium-Substituted Polyoxometalate Network Based on aVanadosilicate Cluster for the Selective Oxidation of Styrene to Benzaldehyde, Inorganic Chemistry, 2020, 59, 9, 5803-5807.

https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c00072

12.  Xing Xin, Na Hu, Yuanyuan Ma*, Yali Wang,Lin Hou, Heng Zhang, Zhangang Han*.Polyoxometalate-based crystalline material as highly sensitive electrochemicalsensor for detecting trace Cr(VI). DaltonTransactions, 2020, 49, 4570-4577.

https://pubs.rsc.org/en/content/articlelanding/2020/DT/D0DT00446D#!divAbstract

13.  Yali Wang, Yuanyuan Ma*, Qing Zhao, LinHou, Zhangang Han*. Polyoxometalate-basedcrystalline catalytic materials for efficient electrochemical detection ofCr(VI). Sensors and Actuators B: Chemical,2020, 305, 127469.

https://www.sciencedirect.com/science/article/pii/S0925400519316685?via%3Dihub

14.  Lin Hou, Yaqi Zhang, Yuanyuan Ma,* YaliWang, Zhifei Hu, Yuanzhe Gao,* and ZhangangHan*. Reduced phosphomolybdate hybrids as efficient visible-lightphotocatalysts for Cr(VI) reduction. InorganicChemistry, 2019, 58, 16667-16675.

https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b02777

15.  Xing Xin, Yuanyuan Ma,* Lin Hou, Yali Wang,Xiaolong Xue, Jin Lin,* and ZhangangHan*. Krebs-type {M2(WO2)2[B-β-SbW9O33]2}n−(M = SbIII, (WO3)) tungstoantimonate possessing uniquepseudo-seesaw Sb−O structure. InorganicChemistry, 2019, 58, 9567-9571.

https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b01343

16.  Xing Xin, Xuerui Tian, Haitao Yu, Zhangang Han*. Synthesis ofhybrid phosphomolybdates and application as highly stable and effectivecatalyst for the reduction of Cr(VI). InorganicChemistry, 2018, 57, 11474-11481.

https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.8b01321

17.  Xuerui Tian, Lin Hou, Jiaojiao Wang, Xing Xin, Heng Zhang, Yuanyuan Ma, Yali Wang,Lina Zhang, Zhangang Han*. Novelfully reduced phosphomolybdates for highly efficient removal of inorganichexavalent chromium and organic dye methylene blue. DaltonTransactions, 2018, 47, 15121-15130.

https://pubs.rsc.org/en/content/articlehtml/2018/dt/c8dt03250e

18.  Zhangang Han*, Xing Xin, RanZheng, Haitao Yu. Influence of Pb element on the catalytic properties of {P4Mo6}-polyoxometalatefor redox reactions. DaltonTransactions,2018, 47, 3356-3365.

http://pubs.rsc.org/en/Content/ArticleLanding/2018/DT/C7DT04772J#!divAbstract

19.  Xuerui Tian, Xing Xin, Yuanzhe Gao, ZhangangHan*. Supramolecular cooperative interaction-induced assembly ofphosphotungstate polyanions and sulfur-containing pyridine-based cations. CrystEngComm,2018, 20, 1588-1596.

http://pubs.rsc.org/en/Content/ArticleLanding/2018/CE/C8CE00026C#!divAbstract

20.  Xiaoxiao Wang,Jiaojiao Wang, Zongke Geng, Zhao Qian andZhangang Han*, Phosphomolybdate assembly as a low-cost catalyst for thereduction of toxic Cr(VI) in aqueous solution, DaltonTransactions, 2017, 46(24),7917-7925. http://pubs.rsc.org/en/Content/ArticleLanding/2017/DT/C7DT01448A#!divAbstract

21.  Zhangang Han*, HuixiaZhang,DeshunZhang,ChunnaLiu,Ran Zheng, GuibinXia,and Xiaoxiao Wang, Sandwich-Type Polyoxotungstate Consistingof Two Different Trilacunary Keggin-Type Units, Inorganic Chemistry, 2016,55(24), 12488-12491.

http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b01848

22.  Weijie Wang, Zhangang Han*, Xiaoxiao Wang, Chuan Zhao, Haitao Yu, PolyanionicClusters [M(P4Mo6)2] (M = Ni, Cd) as EffectiveMolecular Catalysts for the Electron-Transfer Reaction of Ferricyanide toFerrocyanide, Inorganic Chemistry, 2016, 55(13), 6435-6442.

http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b00426

23.  ZhangangHan*, Huixia Zhang,Jinshuang Yan, Xueliang Zhai, A highly aluminum-doped beta-isomer Keggin-typetungstoaluminate, DaltonTransactions, 2016 45(36), 14044-14048.

http://pubs.rsc.org/-/content/articlelanding/2016/dt/c6dt02618d/unauth#!divAbstract

24.  Kaining Gong, Weijie Wang, Jinshuang Yan, Zhangang Han*, Highly reducedmolybdophosphate as a noble-metal-free catalyst for the reduction of chromiumusing formic acid as a reducing agent, Journalof Materials Chemistry A, 2015,3, 6019-6027.

http://pubs.rsc.org/is/content/articlelanding/2015/ta/c4ta06830k/unauth#!divAbstract

25.  Xueli He, Yunping Liu, Kaining Gong, Zhangang Han*, Xueliang Zhai,Copper−Organic Cationic Ring with an Inserted Arsenic−Vanadium PolyanionicCluster for Efficient Catalytic CrVI Reduction Using Formic Acid, Inorganic Chemistry,2015,54(4), 1215-1217.

http://pubs.acs.org/doi/abs/10.1021/ic5030444

26.  Zhan-GangHan*, Xiao-Qing Chang, Jin-Shuang Yan, Kai-NingGong, Chuan Zhao, Xue-Liang Zhai*, An unusual metallic oxygen clusterconsisting of a {AlMo12O40(MoO2)}, Inorganic Chemistry, 2014, 53(2), 670-672.

http://pubs.acs.org/doi/abs/10.1021/ic402126e

27.  Zhangang Han*, QixiaZhang, Yuanzhe Gao, Xueliang Zhai*, Novel hexagonal {V=O}6-containing sandwich-type clusteraccompanied by In Situ carbon-carbon bond formation of organic cation, Dalton Transactions,2012, 41, 1332-1337.

http://pubs.rsc.org/en/Content/ArticleLanding/2012/DT/C1DT11527H#!divAbstract

28.  Zhangang Han*, Yuanzhe Gao, Xueliang Zhai, Jun Peng, Aixiang Tian, Yulong Zhao, ChangwenHu, Self-Process-Programmed Structural Diversity in Supramolecular AssemblyBased on Polyoxometalate Anion and Halogensubstituted Bipyridine Cation, Crystal Growth & Design, 2009, 9(2): 1225-1234.

https://pubs.acs.org/doi/10.1021/cg8012206

29.  Zhangang Han*, Yuanzhe Gao, Changwen Hu, NoncovalentlyConnected Framework Assembled from Unusual Octamolybdate-Based Inorganic Chainand Organic Cation, Crystal Growth &Design, 2008, 8(4): 1261-1264.

https://pubs.acs.org/doi/10.1021/cg700928p

30.  Zhangang Han*, Yulong Zhao, Jun Peng, Carlos J.Gómez-García, Unusual oxidation of anN-heterocycle ligand in a metal-organic framework,InorganicChemistry, 2007, 46(14):5453-5455.

https://pubs.acs.org/doi/10.1021/ic700432p

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